Accounting for Temperature Effects When Predicting Molecular Weight and Composition Distribution for Gas‐Phase Polyethylene Produced using a Multisite Catalyst
نویسندگان
چکیده
Abstract A dynamic model is developed for gas‐phase ethylene/1‐hexene polymerization with a three‐site hafnocene catalyst. The accurately predicts molecular weight and comonomer composition distributions 15 lab‐scale copolymerization runs performed at different temperatures. experimental used to fit this are temperatures between 60 85 °C. Gas‐phase concentrations measured every 2.7 min throughout each run. Predicted chain‐length discretized aid development, keeping the number of ordinary differential equations manageable. Kinetic parameters reference temperature 81 °C activation energies estimated. Using parameter subset selection techniques, it determined that 53 should be estimated using product characterization reactor data. An additional data set obtained validation, confirming predictive power model. proposed its estimates can operating conditions achieve targeted polymer properties.
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ژورنال
عنوان ژورنال: Macromolecular Theory and Simulations
سال: 2022
ISSN: ['1022-1344', '1521-3919']
DOI: https://doi.org/10.1002/mats.202200023